Ferroelectric Properties of Lead-Free (Bi,La)4Ti3O12 Thin Film Deposited on MTP Cell Structure for High Density FeRAM Device

Author:

Cho K.W.1,Kim N.K.2,Oh S.H.2,Choi E.S.2,Sun H.J.2,Yeom S.J.2,Lee K.N.2,Lee Seoung Soo3,Hong Suk Kyoung2,Choi S.K.4,Hong Tae Whan1,Kim Il Ho,Lee J.I.,Ur Soon Chul1,Lee Young Geun1,Ryu Sung Lim1,Kweon Soon Young1

Affiliation:

1. Chungju National University

2. Hynix Semiconductor Inc.

3. Changwon National University

4. Korea Advanced Institute of Science and Technology (KAIST)

Abstract

Ferroelectric properties of Pb-free (Bi,La)4Ti3O12 (BLT) films were optimized on a newly developed MTP cell structure. BLT films were coated on Pt/IrOx/Ir bottom electrode using sol-gel solutions. The composition of the optimized BLT film was about Bi3.25La0.75Ti3.0O12, which was analyzed by ICP-MS method. The switchable polarization obtained in a 100nm-thick BLT film was about 20 uC/cm2 at the 3 V applied voltage, and the optimized BLT film showed little fatigue loss about 10% up to 1×1011 cycles. The imprint properties of the BLT film were also characterized at 25 °C and 90 °C operating temperature after 125 °C data storage. Regardless of operating temperature, switchable polarization of BLT had a sufficiently large margin for device operation up to 10 years.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference14 articles.

1. S.Y. Lee and Kinam Kim, IEDM Tech. Dig., pp.547-550, (2002).

2. B. Yang, et al., IEDL, Vol. 23, No. 12, (2002).

3. S. Y. Kweon, et al., Jpn. J. Appl. Phys., vol. 41, pp.7327-7331, (2002).

4. B. Yang, et al., Jpn. J. Appl. Phys., vol. 42, pp.1327-1330, 2003. 100 102 104 106 108 1010 1012 -1. 2 -0. 9 -0. 6 -0. 3 0. 0 0. 3 0. 6 0. 9 1. 2 100nm 70nm 50nm Fatigue Cycles Normalized dP; P*-P^ (uC/cm.

5. ) Fig. 5. Fatigue properties of NB-BLT thin films at various thicknesses.

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