Activated Carbon Loaded Lignocellulosic Fibers by Pulp Refining Process for Dye and Metal Ion Absorbing Paper

Abstract

This work developed activated carbon loaded lignocellulosic fibers (kraft pulp) by pulp refining process and used them to form activated carbon paper (AC-paper). AC-paper was used for the removal of dye and heavy metal ions from aqueous solutions. In pulp refining process, kraft pulp was mixed with activated carbon using high consistency refiner with the addition of cationic starch as a binder. The effects of cationic starch and activated carbon concentration on AC-paper properties were investigated. Activated carbon amount of 0, 10, 20, 30, 40 and 50%, and cationic starch amount of 0, 0.25 and 0.50% (% by oven dried weight pulp) were examined. The AC-paper was prepared at basis weight of 60±5 g/m2. Paper mechanical properties, including density, tensile index, burst index, ring crush index, and tear index, were tested according to ISO 5270. The results show that all paper strength properties declined when the amount of activated carbon was increased. Especially, when the activated carbon content above 30%, paper strength was greatly reduced. The improvement of paper strength was observed when with the cationic starch was added. However, the increased of cationic starch amount from 0.25 to 0.50% showed no significantly difference in paper strength. Paper adsorption of dye (methyl orange, (MO)) and heavy metal ions (zinc and iron) were also studied. The AC-paper prepared from fiber with 50% activated carbon and 0.50% cationic starch provided highest adsorption values of both dye and metal ions from aqueous solutions. In this work, the use of 30% activated carbon and 0.50% cationic starch in pulp refining process was chosen as a suitable condition for the preparation of activated carbon loaded fiber because the activated carbon content above 30% could disrupt paper strength. The fiber obtained from this suitable condition gave the paper with adsorption values of 0.62, 16.38 and 16.72 mg/g for MO, Zn2+, and Fe2+, respectively. The developed activated carbon loaded lignocellulosic fibers could be potentially used for various specialty paper products, such as absorbent paper, filter paper and active packaging, in the future.