Affiliation:
1. University of Newcastle
Abstract
In this chapter, we review the Nernst-Planck equation describing the cation interdiffusion coefficient, the two tracer cation diffusion coefficients and the thermodynamic factor in ionic compounds and how it is related to the analogous Darken-Manning relationship in binary alloy systems. We make use of the Onsager flux equations of non-equilibrium thermodynamics to rigorously address the problem. The recently found correction factor to the Nernst-Planck equation is analyzed visually by means of computer simulation
Publisher
Trans Tech Publications, Ltd.
Subject
General Chemical Engineering
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献