Viscous Flow Behaviors of Supercooled Liquids of Pre-Annealed Zr55Cu30Al10Ni5 Bulk Metallic Glasses

Author:

Yamasaki Tohru1,Maeda S.1,Kikuchi Takeyuki1,Fukami Takeshi1,Yoshihiko Yokoyama2,Yamamoto Tokujiro2,Kimura Hisamichi2,Inoue Akihisa2

Affiliation:

1. University of Hyogo

2. Tohoku University

Abstract

Viscous flow behavior in supercooled liquid region of as-cast and pre-annealed Zr55Cu30Al10Ni5 bulk metallic glasses has been examined by using a penetration viscometer under high-speed heating rate of 20, 200 and 400 °C/min. Applied load for the cylindrical-shaped penetration indenter with a diameter of 1 mm was varied from 0.049 N to 0.294 N. Viscosity was quite independent of these applied loads. By pre-annealing the bulk metallic glasses at 400 °C, the density of the glasses increased, while the viscosity and the activation energy for viscous flow in their soopercooled liquid decreased with the pre-annealing treatments. Corresponding measurements of the differential thermal calorimetry (DSC) have been also done.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference4 articles.

1. T. Yamasaki, S. Maeda, Y. Yokoyama, D. Okai, T. Fukami, H. M. Kimura and A. Inoue: Mater. Trans. 46 (2005), 2746-2750.

2. T. Yamasaki, S. Maeda, Y. Yokoyama, D. Okai, T. Fukami, H. M. Kimura and A. Inoue, J. Intermetallics, 14 (2006), 1102-1106.

3. A. Slipenyuk and J. Eckert, Scripta Materialia, 50 (2004), 39-44.

4. J. J. Gilman, Philo. Mag. 37 (1978) 577. Fig 4 High-resolution TEM micrograph and correponding selected area diffraction pattern for the pre-annealed Zr55Cu30Al10Ni5 BMG specimen at 400 °C for 120min.

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