Sm2Fe17 Prepared by Calciothermic Reduction-Diffusion Using Different Iron Powders

Author:

Boareto J.C.1,Soyama Juliano2,Felisberto M.D.V.2,Hesse R.1,Pinto A.V.A.2,Taylor T.R.2,Wendhausen Paulo A.P.2

Affiliation:

1. Federal University of Santa Catarina (UFSC)

2. Universidade Federal de Santa Catarina

Abstract

This paper compares the effect of using different types of iron powders for the preparation of Sm2Fe17 by calciothermic reduction-diffusion (CRD). Three types of iron powder were used: carbonyl, sponge and water atomized. The results show that, when immediately nitrogenated after the CRD process, Sm2Fe17 prepared from sponge and water atomized iron powders yield Sm2Fe17N3-magnets with a high degree of texture. However, after a suitable treatment with hydrogen followed by nitrogenation, Sm2Fe17-powders made from Carbonyl iron produce magnets with the best quality regarding coercivity, remanence and degree of texture.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference9 articles.

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2. J. M. D. COEY, J. F. LAWLER, H. SUN, J. E. M. ALLAN Nitrogenation of R2Fe17 compounds: R=rare earth J. Appl. Phys., 69 3007-3010 (1991).

3. A. VERMA, R. K. SIDHU, S. MAHAJAN, O. P. PANDEY. Effect of Excess Samarium Oxide on the Preparation of Sm2Fe17 Powder by Calciothermic Reduction. Journal of Materials Science Letters 15, 2088(1996).

4. S. BRENNAN, K. KOBAYASHI, J. M. D. COEY, Development of Coercivity in Nitrides of Sm2Fe17 Produced by the Calciothermic Reduction Method 13 Th Int. Workshop on R E Magnets and Their Application, Birmingham, UK, Sept. 795(1994).

5. A. W. TAYLOR, R. P. FERNANDES, P. A. P. WENDHAUSEN, Characterization of the Sm2Fe17 Reduction-Diffusion Process São Paulo. 59th Annual ABM International Congress, 1777 (2004).

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