Affiliation:
1. National Research Tomsk State University
2. National Research Tomsk Polytechnic University
Abstract
The way of the graphite electrodes production, modified by polymeric composition, containing nanoparticles of gold or mercury, for determination of metals’ ions by the method of stripping voltammetry is offered. The influence of copolymer’s structure, nature of solvent, concentration of metal-modifier, viscosity of composition, film’s thickness and conditions of its formation on electrochemical and mechanical characteristics of sensor systems was studied. The approbation of electrodes was carried out using the certified techniques with help of the method of stripping voltammetry during determination of zinc, cadmium, lead, copper, mercury, arsenic, selenium.
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Reference11 articles.
1. G. K. Budnikov, G. A. Evtyugin, V. N. Maystrenko, Modified electrodes for voltammetry in chemistry, biology and medicine, BINOM, Knowledge Laboratory, Moscow (BINOM, Laboratoriya znaniy Moskva – in Russian), (2012).
2. L. G. Shaydarova, G. K. Budnikov, Chemically modified electrodes based on noble metals, polymer films, or their composites in organic voltammetry, Journal of Analytical Chemistry 63(10) (2008) 922-942.
3. N. Yu. Stozhko, N. A. Malakhova, M. V. Fyodorov, Kh. Z. Brainina, Modified carbon-containing electrodes in stripping voltammetry of metals, J. Solid State Electrochem. 12 (2008) 1185-1204.
4. J. Wei, D. Yang, H Chen, Y. Gao, H. Li, Stripping voltammetric determination of mercury(II) based on SWCNT-PhSH modified gold electrode 190 (2014) Pages 968-974.
5. M. Fairulnizan MD Noh, I. E. Tothill, Determination of Lead(II), Cadmium(II) and Copper(II) in Waste-Water and Soil Extracts on Mercury Film Screen-Printed Carbon Electrodes Sensor, Sains Malaysiana 40(10) (2011) 1153-1163.
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