Activation Energy of Pure and Impregnated Lignocellulosic Materials Obtained by Isothermal Method

Author:

Chrebet Tomas1,Jozef Martinka2,Balog Karol3,Turnova Zuzana3

Affiliation:

1. Slovak University of Technology in Bratislava, Faculty of Materials Science and Technology in Trnava, Department of Safety Engineering

2. Slovak University of Technology in Bratislava, Faculty of Materials Science and Technology in Trnava

3. Slovak University of Technology in Bratislava

Abstract

On the base of experimental observations of mass loss rate in dependence of temperature in isothermal condition in circulating air atmosphere was determined the activation energy of lignocellulosic materials degradation without and with retardants. Experiment was performed in an electrically heated hot-air furnace according to ISO 871 standard (Setchkin furnace) in conjunction with precision scales. Degradation of lignocellulosic materials was performed at various temperatures and various air-flow speeds. Pure cellulose as a model compound was impregnated by water solution of KHCO3 and (NH4)2HPO4.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference10 articles.

1. A. Blažek,: Thermal analysis, SNTI, Prague, 1973, ISBN 0 442 00812 0.

2. G. Varga, A. Vážanová: Determination of the activation energy by linear heating method.

3. B.A. Howell, J.A. Ray: Comparison of isothermal and dynamic methods for the determination of activation energy by thermogravimetry, Journal of Thermal Analysis and Calorimetry, Vol. 83 (2006) 1, 63–66.

4. B.A. Howell, Thermochim. Acta, 388 (2002) 275.

5. STN ISO 871: 2006 Plastics – Determination of ignition temperature using a hot-air furnace.

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