Study on CaSO3 and CaO as Additives of Slag Cement

Author:

Gong Guo Zhuo1,Ye Shu Feng2,Li Jin Hong3,Yang Wen Fen4,Xie Qiang5

Affiliation:

1. Beijing Academy of Science and Technology

2. Chinese Academy of Sciences

3. China University of Geosciences

4. Beijing Municipal Institute of Labor Protection

5. China University of Mining and Technology (Beijing)

Abstract

CaSO3and CaO are main components in solid waste from flue gas semi-dry desulfurization process. A series of slag cements were prepared from cement clinker and blast furnace slag, in the process of which CaSO3 and CaO were added. The composition and macrostructure of the derived cements were studied in detail with the aid of XRD and SEM. Furthermore, the influence of amount of CaSO3and CaO on the mechanical properties and setting time for slag cement were evaluated, the mechanisms of which were also discussed. The results show that due to the formation of AFt and AFm in the hydration process, the CaSO3has an obvious setting retarding effect on the slag cement, and quality slag cement can be obtained when the amount of slag and CaSO3are 20% and 2%, respectively, the compressive strengths of which at 3, 7, 28 d are 30.8, 39.1, 53.7 MPa, and bending strengths at 3, 7, 28 d are 9.6, 10, 11.9MPa, respectively. Besides, CaO added which can play a role of alkali-activator for slag cement can not cause the soundness problem of slag cement.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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3. X. LIN and G. LIN, Coal Ash China. (2003) 15-17.

4. B. FU, J. GE, and Y. ZHENG, Electric Power Environmental Protection. 16 (2000) 35-38.

5. W. WANG, L. CUI, C. MA, Y. DONG, and X. XUN, Power System Engineering. 21 (2005) 27-29.

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