Affiliation:
1. Huaqiao University
2. East China University of Science and Technology
Abstract
Novel sp3C1-bridged constrained geometry complexe(CGC) were synthesized, and fulvene was used as initial stuff, they were characterized by 1H-NMR, 13C NMR, MS and EA. The CGC/methylaluminoxane (MAO) system show activation for copolymerization of ethylene and 1-octene under 1.0 atmospheric pressure (Complex 2/MAO, 1.196 × 106 g-Polymer /mol-Zr•h, Pethylene = 1.0 atm, Al/Zr = 1000, time = 30 min,1-Octene content in polymer = 5.46 mol%).
Publisher
Trans Tech Publications, Ltd.
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