Study on Cross-Linking Degree of Polyethylene

Author:

Zou Li Qiu1,Wu Guang Feng1

Affiliation:

1. Changchun University of Technology

Abstract

In this paper, the linear low density polyethylene (LLDPE) was melted and cross-linked by dicumyl peroxide (DCP) used to prepare cross-linked polyethylene (XPE). The gel content was determined by extraction method. The effect of content of cross-linker, cross- linked time, cross-linked temperature and other factors on the gel content were studied. It was found that the extraction time should be 18h for XPE. The gel content increased with the increasing of cross-linked time. When the cross-linked time was 10-15min, DCP was almost complete decomposition. The gel content was basically stable when the cross-linked temperature was 170-175 oC. The maximum of gel fraction was about 90%.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference11 articles.

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3. S M Tamboli, S T Mhaske & D. D. Kale: Cross-linked polyethylene. Indian Journal of Chemical Technology, Vol. 2 (2004), pp.853-864.

4. A. Smedberg, T. Hjertberg, B. Gustafasson: Effect of molecular structure and topology on network formation in peroxide crosslinked polyethylene. Polymer, Vol. 44 (2003), pp.3395-3405.

5. W.M.D. Bryant, F.W. Billmeyer Jr, L.T. Muus, J.T. Atkins, J.E. Eldridge: The Meleculur Structure of Poltethylene.X. Optical Studies of Crosslinked Network, J. Am. Chem. Soc., Vol. 81(1959), pp.3219-3223.

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