Aqueous Synthesis and Thermal Decomposition Behavior of Rare Earth Complexes with <i>o</i>-Carboxylbenzaldehyde-2-Pyrroleformylhydrazone Ligand-Reference-Cited by-同舟云学术

Aqueous Synthesis and Thermal Decomposition Behavior of Rare Earth Complexes with o-Carboxylbenzaldehyde-2-Pyrroleformylhydrazone Ligand

Published:2013-01 Issue: Volume:651 Page:137-142
ISSN:1662-8985
Container-title:Advanced Materials Research
language:
Short-container-title:AMR

Author:

Yang Chun¹,Liu Xiang Rong²,Wang Li Na²,Shen Wen Sheng²,Yang Dao Wu¹

Affiliation:

1. Changsha University of Science and Technology

2. Xi’ an University of Science and Technology

Abstract

Thirteen novel complexeswere synthesized using this method, by employing the designed ligand o-carboxylbenzaldehyde-2-pyrroleformylhydrazone (H2L). Elemental analysis, molar conductivity,Fourier transform infrared (FTIR) spectracharacterizations show that the composition formula of the complexes is RE(HL)(H2L)•2H2O (where RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Y). The thermal decomposition of the thirteen complexes was studied by Subscript textTG-DTG analysis and their apparent activation energies (E) were calculated by Kissinger’s and Flynn-Wall-Ozawa’s methods.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Link

https://www.scientific.net/AMR.651.137.pdf

Reference9 articles.

1. S. V. Eliseeva, D. N. Pleshkov, K. A. Lyssenko, L. S. Lepnev, J. -C. G. Bunzli and N. P. Kuzmina, Deciphering three beneficial effects of 2, 2'-bipyridine-N, N'-dioxide on the luminescence sensitization of lanthanide(III) hexafluoroacetylacetonate ternary complexes, Inorg. Chem. 50 (2011).

2. M. Ballesteros-Rivas, H. Zhao, A. Prosvirin, E. W. Reinheimer, R. A. Toscano, J. Valdes-Martínez and K. R. Dunbar, Magnetic ordering in self-assembled materials consisting of cerium(III) ions and the radical forms of 2, 5-TCNQX2 (X=Cl, Br), Angew. Chem. Int. Ed. 124 (2012).

3. F. T. Edelmann, Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2009, Coord. Chem. Rev. 256 (2012) 1151-1228.

4. F. T. Edelmann, Lanthanide amidinates and guanidinates: From laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films, Chem. Soc. Rev. 38 (2009) 2253-2268.

5. Y. Z. Zhang, X. X. Chen, J. Dai, X. P. Zhang, Y. X. Liu and Y. Liu, Spectroscopic studies on the interaction of lanthanum(III) 2-oxo-propionic acid salicyloyl hydrazone complex with bovine serum albumin, Luminescence. 23 (2008) 150-156.