Optimization of the Reaction of Catalytic Cycloalkylation of Phenol with Cyclohexene-Reference-Cited by-同舟云学术

Optimization of the Reaction of Catalytic Cycloalkylation of Phenol with Cyclohexene

Published:2020-10 Issue: Volume:869 Page:82-87
ISSN:1662-9795
Container-title:Key Engineering Materials
language:
Short-container-title:KEM

Author:

Alekperova Irada I.¹,Aghamaliyev Zaur Z.¹,Veliyeva Firuza M.¹,Rasulov Chingiz K.¹

Affiliation:

1. Y.H. Mammadaliyev Institute of Petrochemical Processes National Academy of Sciences of Azerbaijan

Abstract

The paper presents the results of studies of the reaction of the interaction of phenol with cyclohexene (CH) in the presence of a Zeolite-Y catalyst impregnated with phosphoric acid and studying the dependence on the yield and selectivity of the target product on various parameters. As a result of the study of the phenol cycloalkylation by cyclohexene, optimal conditions were found, the yield of which is 81.6 % of theory for the taken CH, and the selectivity is 94.0 % for the target product. The developed mathematical model of the processes of the interaction of phenol with cyclohexene in the form of a regression polynomial made it possible to find the optimal values of the input variables.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Link

https://www.scientific.net/KEM.869.82.pdf

Reference5 articles.

1. V.G. Mirzayev, Z.Z. Agamaliyev, Ch.K. Rasulov, Some peculiarities of interaction reaction of phenol with the dimerization products of C4 fraction of gasoil pyrolysis, Global Journal of Chemistry. 3 (2017) 136-142.

2. T.N. Nesterova, D.A. Chernyshov, V.A. Shalkin, Sulfonic acid cation exchange resins in the synthesis of straight chain alkylphenols, Catalysis in Industry. 8 (2016) 16-22.

3. I.I. Alekperova, Z.Z. Agamaliyev, F.M. Veliyeva, Ch.K. Rasulov, Optimization of phenol cycloalkylation process with cyclohexene in the presence of catalyst KU-23, Processes of petrochemistry and oil refining. 20 (2019) 424-432.

4. A.A. Sirota, Methods and algorithms for data analysis and their modeling in MATLAB: textbook. Allowance, Publishing house BHV-Petersburg,, St.-Petersburg, (2016).

5. J. Steimel, M. Harrmann, G. Schembecker, S. Engell, Model-based conceptual design and optimization tool support for the early stage development of chemical processes under uncertainty, Computers & Chemical Engineering. 59 (2013) 63-73.