Affiliation:
1. Center for Polymer Technology
Abstract
An effort to improve electrical property of Polypropylene (PP)/Clay nanocomposite was conducted. Carbon black (CB) was introduced into PP/Clay to enhance that property as required for conductive polymer composites (CPCs) application. The compositions of CB on PP/Clay were varied at 3, 5, and 7 percent hundred resin (phr). In this research, all composites were prepared by melt mixing using an internal mixer at 222 °C, 83 rpm, and 10 minutes. A compatibilizer, PP-grafted-Maleic Anhydride (PP-g-MA), was used to facilitate dispersion of clay layers and CB particles on PP matrix. The electrical property of composite was evaluated from their surface resistivity using insulation tester. Meantime thermal-oxidative stability property was analyzed from oxidative induction time (OIT) data using Differential Scanning Calorimetry (DSC) instrument. The presence of CB dramatically decreased surface resistivity of PP/Clay from 6.98 x 1013 ohm to 7.35 x 106 ohm by adding CB 7 phr. OIT of PP/Clay dropped 155% compare with neat PP. On the other hand, the addition of CB 7 phr into PP/Clay improved OIT of PP/Clay up to 22 %. The interlayer structure of clay was investigated using X-ray Diffraction (XRD) to find out the synergistic effect between clay and CB. Actually, clay interlayer spacing did not change due to the addition of CB.
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Cited by
2 articles.
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