Study of the Nature of the Influence of some Oligophosphonates on the Rheological Properties of High-Density Polyethylene

Author:

Shaov Abubekir Kh.1,Beslaneeva Asya N.1,Shustov Gennady B.1,Altueva Albina M.1

Affiliation:

1. Kh.M. Berbekov Kabardino-Balkarian State University

Abstract

High molecular weight compounds with organophosphorus backbones are usually obtained by polycondensation of phosphorus-containing monomers, leading, most often, to products of low molecular weight at low yields. This fact is explained [1] by several reasons: a decrease in the reactivity of the second functional group of the monomer after the first one has reacted; the possibility of the formation of cyclic compounds; hydrolytic instability of the phosphorus-heteroatom bond (usually P-O, P-N), etc.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference10 articles.

1. Encyclopedia of Polymers /In 3 volumes. Ed. board: V.A. Kargin (chief editor) [and others], Sov. Ents., 1972. - 1224 p.

2. Kirpichnikov P.A., Mukmeneva N.A., Pobedimsky D.G. Organophosphate stabilizers of polymers: effectiveness and mechanisms of action. - Advances in chemistry. - 1983. - Vol. 52. - No.11. - P. 1831-1851.

3. Barshtein R.S., Kirillovich V.I., Nosovskiy Yu.E. Plasticizers for polymers. - M.: Chemistry. - 1982. - 200 p.

4. Pavlova S.-S.A., Zhuravleva I.V., Topchinsky Yu.I. Thermal analysis of organic and high molecular weight compounds. - M.: Chemistry. - 1983. –120 p.

5. Emanuel N.M. Basic research tasks for polymer stabilization. - Bulletin of the USSR Academy of Sciences. - 1969. - No. 7. - P. 41-47.

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