Affiliation:
1. Russian Academy of Sciences
Abstract
Nowadays, hyperbranched polymers (HBP) are obtained by different polycondensation and polyaddition reactions [1]. Almost interest is the reaction of 1,3-dipolar cycloaddition of azides to alkynes (1,3-DCA) [2, 3]. There is a series of papers dedicated to the preparation of triazine-triazole HBPs [4, 5, 6]. These polymers were obtained by the reaction of azido-acetylene AB2 monomers polyaddition: 2-azido-4,6-bis (propyne-2-yloxy) -1,3,5-triazine (ABPOT) and 2,4-diazido-6- (propine-2-yloxy) -1,3,5-triazine (DAPOT) (Fig. 1).
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Reference16 articles.
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2. R. Huisgen, 1, 3‐dipolar cycloadditions. Past and future, Angewandte Chemie International Edition. 2 (1963) 565-598.
3. V. O. Rodionov, V. V. Fokin, M. G. Finn, Mechanism of the Ligand‐Free Cu(I)‐Catalyzed Azide–Alkyne Cycloaddition Reaction, Angewandte Chemie. 117 (2005) 2250-2255.
4. G. V. Malkov et al., New polynitrogen hyperbranched polymers, Russian Chemical Bulletin. 60 (2011) 1940-1943.
5. G. V. Malkov et al., New hyperbranched poly ([1, 2, 3]-triazole-[1, 3, 5]-triazines), Polymer Science Series B. 49 (2007) 301-304.
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