Abstract
In the lost foam casting (LFC) of aluminum alloys, the expandable polystyrene (EPS)
foam characteristics (foam composition, polymer processing and bead fusion) influence the
formation of deleterious fold defects in the final casting. In this research, four types of EPS beads
were investigated: (1) the regular EPS beads, (2) 2wt% hexabromocyclododecane and 2wt%
dicumyl peroxide added to the EPS beads during the polymerization process, (3) 2wt% silicaalumina
blended to EPS beads after the pre-expansion process of the beads and (4) 2wt%
hexabromocyclododecane blended to EPS beads after the pre-expansion process of the beads. The
density of the regular and modified EPS beads was kept constant at 25.63 kg/m3. Aluminum alloy
A356 was poured at 1023 K into the window pattern. The window patterns with regular EPS beads
did not fill completely and had identifiable carbon/oxide defects on the surface. The window
patterns with the additives were completely filled with a few surface defects. From
thermogravimetric analysis (TGA), it was found that the EPS beads with silica-alumina had a
reduced onset temperature of degradation of EPS (from 634 K to 618 K) and a reduced activation
energy (from 188 kJ/mol to 147 kJ/mol) relative to the regular beads. In the organic brominatedmodified
EPS (both through blending and polymerization), it was found that the value of the
preexponential (rate equation) was significantly increased. Through light optical microscopy
(LOM) and scanning electron microscopy (SEM), it was found that the polymerization process
additives increased the degree of bead fusion whereas the post pre-expansion additives decreased
the degree of bead fusion. Finally, the EPS beads treated during the polymerization process
produced castings with the least overall surface, subsurface and internal defects.
Publisher
Trans Tech Publications, Ltd.
Reference6 articles.
1. H. F. Shroyer, U. S. Patent 2, 830, 343. (1958).
2. R. J. Donahue, U. S. Patent 5, 960, 851. (1999).
3. P. Gardner, R. S. Lehrle and D. Turner, Polymer degradation modified by blending with polymers chosen on the basis of their φ-factors, Journal of Analytical and Applied Pyrolysis Vol. 25 (1993), p.11.
4. M. H. Warner, B. A. Miller and H. E. Littleton, Pattern Pyrolysis Defect Reduction in Lost Foam Casting, AFS Transactions Vol. 106 (1998), p.777.
5. F. Sonnenberg and M. E. Hoover, Development of the Improved Casting Bead for Lost Foam, LFC Conference 2004, Paderborn, Germany, March 31-April 1 (2004).
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