Synthesis, Spectroscopic Properties of Bis-Boc-L-Alanine Modified 1,8-Naphthyridine Ligand Induced by Hg2+

Abstract

One Bis-Boc-L-alanine-1,8-naphthyridine ligand containing amino acid by amido bond named 2,7-Bis-Boc-L-alanine-1,8-naphthyridine (L1) was synthesized and characterized. And there absorption and fluorescence spectra in methanol is presented. It exhibits electronic absorption spectra with λmax at about 340 nm, which can be tentatively assigned to π→π* transition. The emission spectra of L1 in CH3OH shows a mirror symmetry peak with λmax at about 375 nm. Then, the comprehensive study of spectroscopic properties upon titration of L1 with heavy metal ions as ion source in CH3OH was investigated.