Study on Morphology and Mechanical Properties of Polyaspartic Esters Based Polyureas

Author:

Huang Wei Bo1,Lu Ping1,Zhang Jing1,Li Xin Mao1

Affiliation:

1. Qingdao Technological University

Abstract

The morphology, shock absorption and dynamic mechanical properties of a new architectured multifunctional materials- polyaspartic esters (PAE) based ployureas were investigated through FTIR, atomic force microscope(AFM), drop-weight test and dynamic mechanical analysis(DMA). The PAE based polyureas were prepared from synthesized PAE and hexamethylene diisocyanate(HDI)trimer /polytetramethylene ether glycol (PTMG) prepolymer. The FTIR results indicated that hydrogen-bonded urea carbonyl of PAE based polyurea was 76.1%, and the length of hydrogen bonding was 0.306nm. The microphase separation phenomenon of the PAE based polyureas were observed directly through AFM topography studies. PAE based polyureas exhibited unique shock absorption and dynamic mechanical properties.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference8 articles.

1. HUANG Weibo. Technology of Spray Polyurea. (Chemical Industry Press, Beijing 2005).

2. Lu Ping, Chen Guohua, Huang Weibo. Journal of Chemical Engineering of Chinese Universities, Vol. 22 (2008), pp.106-112.

3. LU Ping, CHEN Guohua, HUANG Weibo. Polymer Materials and Engineering, Vol. 23 (2007), pp.55-58.

4. Lu Ping, Chen Guohua, Huang Weibo. Journals in Wuhan University of Technology, Vol. 29(2007), pp.61-63.

5. Kross R D, Nakamoto K, Fassel V A. Spectrochimica Acta, Vol. 8(1956), pp.142-151.

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