Vapour Phase Surface Graft Polymerization of Acrylonitrile onto Poly(ethylene terephthalate) Film

Author:

Zhu Jian Wu1,Deng Jian Ping1,Zhao Hong Chi2,Liang Shu Jun1,Yang Wan Tai1

Affiliation:

1. Beijing University of Chemical Technology

2. Hebei University

Abstract

In this study the vapour phase surface graft polymerization of acrylonitrile (AN) onto poly(ethylene terephthalate) (PET) film was conducted with benzoyl peroxide (BPO) as an initiator. Effects of reaction time and quantity of BPO on the polymerization were investigated. With the prolongation of reaction time, the graft polymerization took place rapidly at first, then slowed down, and leveled off. With the increase of BPO, the graft yield increased, then remained unchanged, and lastly began to decrease. The surface topography structure of the grafted PET film was observed by SEM. Grafted PET film was characterised by FTIR spectra, SEM photographs and contact angle measurement.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference9 articles.

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