The New Method to Separate Stannum and Copper in the Process of Refining Tin

Author:

Zhang Bo1,Liu Da Chun1,Xiong Heng1,Zhou Zhen Gen2,Li Xu3,Li Ling4,Yang Bin1,Gu Xu Peng1,Wang Shuang Ping4

Affiliation:

1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization

2. Beijing University of Science and Technology

3. General Research Institute for Nonferrous Metals

4. Kunming University of Science and Technology

Abstract

As the ancient metal, Sn is widely used in all aspects of human life. Nowadays, S, as the vulcanizing agent, is used in the process of refining tin to separate Cu and Sn. However, there are few reports about the other agent of removing copper from stannum. In this study, SnS, a new sulfiding agent to separate Cu and Sn, was investigated. During the process, SnS replaces the combination of Sn and Cu. The variables considered in the experimental study were reaction temperature, time and the ratio of reactants. The experimental data indicated under certain conditions, the removal rate of Cu reach 94.3%. At last, we studied the vacuum reaction of Cu2S and Sn, results indicated that under appropriate conditions, the Cu is detected. The SnS is formed. And after the vacuum reaction, the SnS could be used recycling. This work presented a promising technology for separating Cu from tin.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference20 articles.

1. Peng Cunqiu. Ti metallurgy, Central South University Press, Hunan, 1991 (in Chinese).

2. Song xingcheng,Tin metallurgy, Metallurgical Industry Press, Beijing, 2011 (in Chinese).

3. Xiujing Zai, Heavy Metal Metallurgy, Metallurgical Industry Press, Beijing, 2011 (in Chinese).

4. Peng Rongqiu, Heavy Metal Metallurgy, Central South University Press, Hunan, 1991 (in Chinese).

5. Yongnian Dai, Bin Yang, Vacuum Metallurgy of Nonferrous Metallic Materials, Metallurgical Industry Press, 2000, p.11–22.

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