New Organic-Inorganic Hybrid Ureasil-Based Polymer Materials Studied by PALS and SEM Techniques

Author:

Kavetskyy Taras1,Šauša Ondrej2,Krištiak Jozef2,Petkova Tamara3,Petkov Plamen4,Boev Viktor3,Lyadov N.5,Stepanov Andrey L.5

Affiliation:

1. Drohobych Ivan Franko State Pedagogical University

2. Slovak Academy of Sciences

3. Institute of Electrochemistry and Energy Systems, Bulgarian Academy of Sciences

4. University of Chemical Technology and Metallurgy

5. Russian Academy of Sciences

Abstract

The new organic-inorganic materials, based on polyether chains covalently linked to a silica framework through urea bridges, referred as ureasilicates or ureasils, and semiconducting As2S3-ureasil composites are investigated using positron annihilation lifetime spectroscopy (PALS) and scanning electron microscopy (SEM) techniques. The results obtained show that incorporation of the As2S3 clusters into ureasil affects on the ortho-positronium (o-Ps) intensity or positronium formation probability and micro-/nanoscopic structure compared to the pure polymer, the effect is more essential as the loading fraction of As2S3 increases.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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