Synthesis of Functional Ceramic Materials for Application in 2 kW Stationary SOFC Stacks
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Published:2012-11
Issue:
Volume:730-732
Page:147-152
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ISSN:1662-9752
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Container-title:Materials Science Forum
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language:
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Short-container-title:MSF
Author:
Martinelli Antonio E.1, Macedo Daniel A.1, Cesário Moisés R.1, Cela Beatriz2, Nicodemo Juliana P.1, Paskocimas Carlos A.1, Melo Dulce Maria de Araújo1, Nascimento Rubens M.1ORCID
Affiliation:
1. Universidade Federal do Rio Grande do Norte 2. Forschungszentrum Jülich GmbH
Abstract
This paper presents an overview of recent advances in the synthesis and preparation of solid oxide fuel cells (SOFCs) functional ceramic materials, focusing on low-/intermediary-temperature SOFCs. Novel synthesis processes for oxygen ion-conducting and mixed electronic and ionic conductors, fundamental to reduce the operating temperature of SOFCs were studied. Ni-Ce0.9Gd0.1O1.95 (Ni-CGO) anodes were successfully synthesized by the so called “one step synthesis”. La0.5Sr0.5Co0.8Fe0.2O3 (LSCF), Ce0.8Sm0.2O1.9 (SDC) and their mixture were produced as a cobaltite-based composite cathode by mixing powders synthesized by microwave-assisted combustion and the modified polymeric precursor method, respectively. Preliminary electrochemical activity tests with the synthesized electrodes were performed in electrolyte-supported SOFCs using commercially available 200 µm thick yttria stabilized zirconia (8YSZ) as electrolyte. The maximum power density of 52 mW/cm2 was reached at 850 °C. This result can be further improved replacing thick YSZ electrolytes by doped-ceria thin films, aiming at operation temperatures of 500–800 °C and power densities as high as 800 mW/cm2. The assembling of anode-supported cells with the configuration Ni-CGO/CGO (10 µm thickness)/LSCF-SDC are for applications in 2 kW stacks are currently under way.
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science
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