Structural Evolution of FeAl3 Intermetallic during High-Energy Ball-Milling

Author:

López-Miranda J. Luis1,Romero-Romero J.R.1,Esparza R.2,Rosas G.1

Affiliation:

1. UMSNH

2. Universidad Nacional Autónoma de México (UNAM)

Abstract

In this work, we reported the results obtained by the structural characterization of the FeAl3 intermetallic compound. This material was synthesized by conventional casting technique using Fe (99.97%) and Al (99.92%) elemental metals. Then, the as-cast alloy was subjected to high-energy ball-milling for different times (1, 2.5, 5, 7.5, 10 and 15 h). The characterization of the alloy was performed by X-ray diffraction patterns, scanning and transmission electron microscopy. The results show that FeAl3 intermetallic was produced as a single-phase after conventional casting. The milled experiments show that the FeAl3 (monoclinic) transforms to Fe2Al5 (orthorhombic) after 15h of milling. Therefore, this phase transformation is characterized by a change from low to high symmetry systems.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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2. Hydrogen generation by aluminum hydrolysis using the Fe2Al5 intermetallic compound;International Journal of Hydrogen Energy;2016-02

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