Influence of Manganese and Tin Substitution on the Structure and Magnetic Properties of CdCr2Se4

Author:

Jendrzejewska Izabela1,Zajdel Paweł2,Mroziński Jerzy3,Maciążek Ewa1,Goryczka Tomasz2,Hanc Aneta2,Kita Andrzej1

Affiliation:

1. Silesian University

2. University of Silesia

3. Wrocław University

Abstract

Single phase materials with general formula CdxMeyCr2Se4 (where Me = Mn, Sn) were obtained using solid state synthesis method. Both compounds are ferromagnets with TC =115K (Sn) and 135K (Mn). The values of Curie-Weiss parameter ΘC-W = 135K (Sn) and 145K (Mn) are higher than respective values of TC indicating a presence of competing antiferromagnetic component. The values of lattice parameters are consistent with Sn and Mn replacing Cd. Slight cadmium deficiency has been also observed.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

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