Influence of Temperature Independent Contribution of Magnetic Susceptibility on the Curie-Weiss Law

Author:

Groń Tadeusz1,Pacyna Andrzej W.2,Malicka E.1

Affiliation:

1. University of Silesia

2. Polish Academy of Sciences

Abstract

A fitting procedure of the Curie-Weiss law, eliminating the temperature independent contribution (0) from the experimental susceptibility data, was used for determination of the magnetic parameters, i.e. a Curie constant, a Curie-Weiss temperature and an effective magnetic moment, because the theoretical considerations showed that the Curie-Weiss law is invalid for 0  0, even small. This method revealed for the HgCo(NCS)4 paramagnet, commonly accepted as a magnetic susceptibility standard, 0 = 2.43710-6 cm3/g, while for the ZnCr2Se4 antiferromagnet, known as a matrix of various diluted systems, – 0 = -2.56610-6 cm3/g, for comparison.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

Reference14 articles.

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2. B.N. Figgis and R. S. Nyholm: J. Chem. Soc. Vol. 11 (1958), p.4190.

3. S.A. Kuzaiev, P.W. Usatchiev and W.M. Ubin: Fiz. Tver. Tela Vol. 13 (1971), p.2829.

4. D.B. Brown, V.H. Crawford, J.W. Hall and W.E. Hatfield: J. Phys. Chem. Vol. 81 (1977), p.1303.

5. D. Nelson and W. ter Haar: Inorg. Chem. Vol. 32 (1993), p.182.

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