The Characteristics of All-Optical Switching and Modulation in Phenoxy-Phthalocyanines Liquid

Abstract

We present our experimental results on the measurements of excited state dynamics in 2, 9, 16, 23-phenoxy-phthalocyanine (Pc1) and 2, 9, 16, 23-phenoxy-phthalocyanine-zinc (Pc2) using the pump-probe experiment. The results show that the All-Optical Switching (A-OS) response time of Pc2 longer than that of Pc1, and switch-off and -on times of A-OS for Pc2 are 1.2 and 11.6 μs and for Pc1 are 2.3 and 7.8 μs at the same intensity. Moreover, analysis of modulation characteristics of A-OS shows that the stronger the light intensity of the pump light is, the smaller the normalized transmittance is and the shorter the response time of A-OS is. The consequences of such short lifetimes are also discussed in view of the strong A-OS properties of these molecules.