Affiliation:
1. Changsha University of Science and Technology
Abstract
Industrial fresh fluorgypsum was found to be an efficient solid acid catalyst (10 % gmmol-1loading) for Beckmann rearrangement, which promoted conversion of various ketoximes to the corresponding amides or lactams in toluene at reflux temperature. This is the first example of the application of the fluorgypsum as catalyst in organic synthesis, which opens up a new aspect for the utility of the solid waste fluorgypsum.
Publisher
Trans Tech Publications, Ltd.
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