Affiliation:
1. Yiwu Industrial and Commercial College
2. Jiangnan University
3. Beijing Institute of Graphic Communication
Abstract
Subscript text
Subscript textEpoxy resins have been widely used for inner coating in food can and other chemical products storage containers. Differential scanning calorimetry (DSC) was used at different heating rates to study the cure kinetics of the diglycidyl ether of bisphenol A (DGEBA) with a methanol etherified amino resin (MEAR). The apparent activation energy derived from Kissinger and Ozawa methods is 35.67KJ/mol and 40.27kJ/mol, respectively. The reaction order evaluated by Crane equation is 0. 95 and the frequency factor is 1.12×104s-1. Reaction mechanism was monitored by FTIR spectra of the reaction mixtures before and after curing. The curing reaction below 200°C is between alkoxylmethyl (>NCH2OCH3) and epoxide group, not between alkoxylmethyl and hydroxyls.
Publisher
Trans Tech Publications, Ltd.
Reference10 articles.
1. Huang Yanhui, Chen Gang: China Package, Vol. 5 (2005), pp.47-48.
2. Guo Yalin, Liang Guozheng, Qiu Zheming, et, al: Aerospace Materials& Technology, Vol. 36(2006), pp.30-33.
3. Li Guilin. Epoxy Resin and Epoxy Paint (Chemical Industry Press, china, 2003).
4. H.H. Lee, K.S. Chou and Z. W Shih: Int J Adhes, Vol. 25(2005), p.437–441.
5. R. Cervellera, X. Ramis, J.M. Salla, A. Mantec´on, A. Serra, J. Polym. Sci. Part A: Polym. Chem. Vol. 43 (2005) 5799.
Cited by
5 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献