Abstract
Six binary silane systems were chosen to calculate the activity coefficients (γ) and free energies of mixing (ΔGm). These systems included: methyldichlorosilane + methyltrichlorosilane, methyldichlorosilane + methylvinyldichlorosilane, methyldichlorosilane + toluene, methyltrichlorosilane + methylvinyldichlorosilane, methyltrichlorosilane + toluene, methylvinyldichlorosilane + toluene. Based on the Antoine constants, critical parameters of the pure components and Wilson model parameters, γ and ΔGmwere calculated. The influence factors of these thermodynamic properties were also discussed.
Publisher
Trans Tech Publications, Ltd.
Reference29 articles.
1. Z.M. Qiu, X.L. Xie, M. Luo and F.X. Xie: J Zhejiang Univ. SCI. Vol. 6B(6)(2005), p.559.
2. Z.M. Qiu, X.L. Xie S.X. u,W.Y. Chen and F.X. Xie: J Zhejiang Univ. SCI. Vol. 6B(10)(2005), p.1033.
3. Z.M. Qiu X.L. Xie Y.B. He,F.X. Xie and Y.P. Ding: Fluid Phase Equilibria. Vol. 242(2006), p.118.
4. S.X. u,Z.B. Yu, Z.M. Qiu and W. Sun: Chinese J. Chem. Eng. Vol. 11(2003), p.213.
5. P. Colonna N.R. Nannan and E.W. Lemmon: Fluid Phase Equilibria. Vol. 244(2006), p.193.