Structure and Properties of A Dimer Complex: [Co2(Hdmg)2(dien)2](ClO4)24.5(H2O)-Reference-Cited by-同舟云学术

Structure and Properties of A Dimer Complex: [Co₂(Hdmg)₂(dien)₂](ClO4)₂4.5(H₂O)

Published:2013-08 Issue: Volume:372 Page:80-83
ISSN:1662-7482
Container-title:Applied Mechanics and Materials
language:
Short-container-title:AMM

Author:

Liu Xuan Wen¹,Zhong Bing Wen¹,Zhang Yue Hong¹,Guo Rui¹

Affiliation:

1. Northeastern University at Qinhuangdao

Abstract

A new complex crystal [Co2(Hdmg)2(dien)2](ClO4)24.5(H2O) (H2dmg= dimethylglyoxime, dien = diethylenetriamine) had been synthesised in aqueous solution and was characterized by X-ray diffraction and IR spectrum. The complex crystallizes in monoclinic space groupC2/cwith cell constants =20.868(7)Å, =11.408(4)Å, =15.816(4)Å, =90.00°, =116.97(2)°, =90.00°, =3355.8(17)Å3, =4, (000)=1732. The cobalt atom lies in a distorted octahedron environment and coordinates with one oxygen atom from neighbour Hdmg and five nitrogen atoms from bidentate chelate Hdmg and tridentate chelate dien. The two Hdmgs bridge two cobalt atoms to form a six-number Co2O2N2ring.

Publisher

Trans Tech Publications, Ltd.

Link

https://www.scientific.net/AMM.372.80.pdf

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