Segregation and Phase Transitions in Grain Boundaries

Author:

Bokstein Boris1,Rodin Alexey1,Itckovich Aleksei2,Klinger Leonid3

Affiliation:

1. National University of Science and Technology “MISiS”

2. National University of Science and Technology -"MISiS"

3. Israel Institute of Technology

Abstract

The paper is devoted to some properties of grain boundaries: Segregation and concentration phase transitions – two important consequences of atomic interactions in grain boundaries. Except of a short description the Gibbs method of surface excesses and grain boundary segregation isotherms with the limited number of segregation sites in grain boundary, the paper concentrates on the effects of complexes formation, including thermodynamic and computer modeling, and concentration phase transition in the grain boundaries in systems with restricted solubility and intermediate compounds.

Publisher

Trans Tech Publications, Ltd.

Subject

General Chemical Engineering

Reference32 articles.

1. D. McLean, Grain Boundaries in Metals, Clarendon, Oxford (1957).

2. J. R. Manning, Diffusion Kinetics for Atoms in Crystals, Von Nostrand, Princeton (1968).

3. H.Gleiter and B. Chalmers, High-Angle Grain Boundaries, Pergamon (1972).

4. B. Bokstein, Ch. Kopetsky and L. Shvindlerman, Thermodynamics and Kinetics of Grain Boundaries in Metals, Metallurgy, Moscow (1986), in Russian.

5. I. Kaur, Y. Mishin and W. Gust, Fundamentals of Grain and Interphase Boundary Diffusion, Wiley, Chichester (1995).

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