Study on the Performance of Aluminum Thick Film Contacts for Silicon Solar Cells

Author:

Fu Ming1,Li Hong Yong1,Jin Gong Lei1,Fan Lin2,Chen Dong2,Feng Zhao2

Affiliation:

1. Huazhong University of Science and Technology

2. Wuhan Supernano Optoelec Technology Co. Ltd.

Abstract

Aluminum rear contacts of silicon solar cells are made commonly by screen-printing aluminum paste and sintering process. Aluminum thick film contacts have a direct effect on photoelectric properties of solar cells, like open circuit voltage (Voc), short circuit current (Isc), conversion efficiency (η), etc. The principle of Al-back surface field (BSF) has been studied in this paper. With thermal gravimetric analysis and differential scanning calorimetry (TGA-DSC) method, the chemical reactions between aluminum thick film and silicon substrate during heat treatment have been investigated. The microstructure of aluminum thick film contacts were analysed by SEM. The electrical properties of Al-BSF are improved by adding a proper amount of nano silicon to the aluminum paste.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference6 articles.

1. A.F. Carroll, D.E. Poser, R. J.S. Young, et al., Advances in PV metallization technology, 20th European Photovoltaic Solar Energy Conference, Barcelona, 2005, pp.906-909.

2. M. Fu, D. Chen, X. Ding, L. Fan, Discussion of several common problems in Al-back surface field (BSF) of silicon solar cells, Proceedings of the 11th China Solar Photovoltaic Conference and Exhibition, Nanjing, 2010, pp.88-91.

3. M. Eberstein, H. Falk-Windisch, M. Peschel, et al., Sintering and contact formation of glass containing silver pastes, Energy Procedia. 27 (2012) 522-530.

4. M. Fu, G.L. Jin, X. Ding, L. Fan, D. Chen, Study on properties of thick-film front silver electrodes for silicon solar cells, Key Engineering Materials. 537 (2013) 209-213.

5. G. Schubert, Thick film metallization of crystalline silicon solar cells, Ph.D. dissertation, University of Konstanz, (2006).

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