Crystal Structure of Biammonium Hexamolybdonickelate (II) Hydrate, (NH4)2(NiMo6O24)(H3O)6

Author:

Liu Hai Xing1,Liu Qing2,Fan Quan Hua1,Zhang Xiao Ping1,Wang Lin Tong1,Ye Kai Qi2,Zeng Guang2

Affiliation:

1. Weifang University

2. Jilin University

Abstract

A novel Ni metal complex H26Mo6N2NiO30has been synthesized from hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. H26Mo6N2NiO30, Monoclinic, P2(1)/c. a = 11.3487(14) Å, b = 11.0823(13) Å, c = 11.9350(16) Å. alpha=gamma= 90°. beta= 108.542(2)°. V= 1423.1(3) Å3. It is also striking that the structure of title compound exhibits extensive hydrogen-bonding interactions among water molecules, ammonium cation, and oxygen atoms in the heteropolyanion.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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