Preparation and Characterization of Polysulfone Membrane for Gas Separation

Author:

Jusoh Norwahyu1,Keong Lau Kok1,Mohd Shariff Azmi1

Affiliation:

1. Universiti Teknologi PETRONAS

Abstract

Symmetric and asymmetric polysulfone membranes were fabricated using different of solvents; N-methyl-pyrrolidone (NMP), Tetrahydrofuran (THF) and Dimethylacetamide (DMAC) at different polymer concentration (15 and 20%) to study the influence of varying type of solvents and polymer concentration in membrane fabrication. The membranes were characterized using Field Emission Scanning Electron Microscopy (FESEM), Thermogravimetric Analyzer (TGA), Universal Testing Machine (UTM) and Fourier Transform Infra-Red (FTIR).The results disclosed that the symmetric, higher polymer concentration membrane contributed to better thermal and mechanical stabilities. PSF/THF membrane showed good mechanical strength while PSF/DMAC membrane illustrated great thermal stability. 20% of polymer concentration and PSF/THF membrane led to the thicker skin layer and dense structure formation.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference19 articles.

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2. W.J. Schell, C.D. Houston, In Membrane Gas Separations for Chemical Process and Energy Application, in: Indusrial Gas Separation, 1983, pp.125-143.

3. I. Cabasso, K.A. Lundy, method of making membranes for gas separation and the composite membranes, in, United States, (1986).

4. M. Mulder, Basic Principles of Membrane Technology Second Edition, 2 ed., Kluwer Academic Publishers, Netherlands, (1996).

5. B.C. Ng, H. Hasbullah, A.F. Ismail, W.A.W. Abdul Rahman, Formation of asymmetric polysulfone flat sheet membrane for gas separation: rheological assessment, in: Regional Symp on Membrane Sci and Technology Johor, Malaysia, (2004).

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