The Synthesis of Novel Chiral Ferrocenyl Aziridino Alcohol Ligands with Two Stereogenic Carbons and Structural Characteristics-Reference-Cited by-同舟云学术

The Synthesis of Novel Chiral Ferrocenyl Aziridino Alcohol Ligands with Two Stereogenic Carbons and Structural Characteristics

Published:2012-05-14 Issue: Volume:518-523 Page:266-271
ISSN:1662-8985
Container-title:Advanced Materials Research
language:
Short-container-title:AMR

Author:

Wang Qian¹,Hou Xue Hui²,Wang Min Can³

Affiliation:

1. Radio and TV University of Henan

2. Zhengzhou College of Animal Husbandry Engineering

3. Zhengzhou University

Abstract

L-threonine (2S,3S) was obtained from easily available L-threonine (2S,3R) after four steps,then seven chiral ligands 9a-9g were prepared by the esterification,condensation,reductive alkylation,cyclization,then reduction with treatment with RMgX.All seven kinds of novel compounds were characterized by 1HNMR,13CNMR,IR and HRMS.Compound 9a was further characterized by X-ray diffraction.The X-ray structure analysis revealed that an intermolecular hydrogen bond is present.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Link

https://www.scientific.net/AMR.518-523.266.pdf

Reference6 articles.

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