X-Ray Investigations of Polycrystalline Compounds with General Formula ZnCr2-xNdxSe4

Author:

Jendrzejewska Izabela1,Zajdel Paweł1,Goryczka Tomasz1,Maciążek Ewa2,Mrzigod Janusz1

Affiliation:

1. University of Silesia

2. Silesian University

Abstract

Abstract. The polycrystalline compounds in the ZnCr2-xNdxSe4 system were prepared by the ceramic method in closed silica tubes using ZnSe, Nd2Se3, and Cr2Se3 as starting materials. The chemical composition and structural data has been determined by X-ray diffraction. The observed symmetry is cubic, space group . For ZnCr1.95Nd0.05Se4 compounds, a pure spinel phase forms for stoichiometric and smaller amounts of ZnSe. For both compounds of ZnCr1.90Nd0.10Se4, near spinel phase, a foreign ZnSe phase exists. It may indicate that 10% doping is close to the solubility limit of Nd in ZnCr2Se4.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

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