Oxygen Passivation of Rhodium and Platinum with Direct Current Polarization in 12 m Hydrochloric Acid Solution

Author:

Kuzas E.A.1,Voinov V.N.1,Potapov P.S.1

Affiliation:

1. Ural Federal University

Abstract

It was found that the surfaces of rhodium and platinum electrodes with polarization by direct current in 12 M hydrochloric acid solution are completely covered with oxygen atoms at a potential of +0.68 V (relative to the reference hydrogen electrode), and its increase rate is 10–90 mV/s.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

Reference20 articles.

1. F.K. Crundwell [et al.], Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals, Elsevier, Oxford, (2011).

2. E.A. Kuzas, The Dissolution of Raw Materials Containing Platinum Group Metals Under the Action of Electric Current, Dissertation of the Candidate of Technical Sciences, Ekaterinburg, (2018).

3. J. Llopis, I.M. Tordesillas, M. Muñiz, Anodic Corrosion of Rhodium in Hydrochloric Acid Solutions, J. Electrochimica Acta. Vol. 10, Issue 11 (1965) 1045–1055.

4. J. Llopis, M. Vázquez, Passivation of Rhodium in Hydrochloric Acid Solutions, J. Electrochimica Acta. Vol. 9, Issue 12 (1964) 1655–1663.

5. L.I. Kadaner, Electrodeposition of Precious and Rare Metals, Tekhnika, Kiev, (1974).

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