α-MoO3 Nanostructure Synthesized in Plasma by an Original Method of Pulsed High-Voltage Discharge as Highly Reversible Anode for Secondary Lithium-Ion Battery

Abstract

A new concept for synthesis of the nanostructured transition metal oxides had been proposed. In particular, the method of pulsed high-voltage discharge was adopted for synthesis of α-MoO3 nanostructure with orthorhombic crystal lattice. The as-prepared α-MoO3 was investigated as anode for Li-ion battery. The 30-fold charge–discharge cycling has shown that material specific capacity (approximately 90 mAh g–1) is not high, however excellent reversibility was achieved (the Coulombic efficiency equals to 99.9%). Thus the method opens new ways for the synthesis of nanomaterials with stable reversible capacities for Li-ion batteries.