Affiliation:
1. Dresden University of Technology
2. Lviv Polytechnic National University
3. Universität Bayreuth
4. Kurt-Schwabe Research Institute
Abstract
Crystal structure,thermal expansion, oxygen non-stoichiometry, electrical conductivity and diffusion characteristics of two analogous LaFe0.7Ni0.3O3‑d and PrFe0.7Ni0.3O3‑d compositions were investigated depending on temperature (201000 °C) and oxygen partial pressure (0.6–21000 Pa). The found oxygen diffusion and oxygen exchange coefficients for the both compositions at similar conditions are near to each other and varied in the range of 110‑7110‑5 cm2s‑1 and 510‑6110‑4 cms‑1, respectively.
Publisher
Trans Tech Publications, Ltd.
Subject
Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics
Reference13 articles.
1. E.P. Murray, M.J. Sever, S.A. Barnett, Electrochemical performance of (La, Sr)(Co, Fe)O3- (Ce, Gd)O3 composite cathodes, Solid State Ionics 148 (2002) 27-34.
2. S. Hashimoto, K. Kammer, F.W. Poulsen, M. Mogensen, Conductivity and electrochemical characterization of PrFe1−xNixO3−δ at high temperature, J. Alloys Compd. 428 (2007) 256261.
3. R. Kumar, R. Choudhary, M. Ikram, D. Shukla, S. Mollah, P. Thakur, K. Chae, B. Angadi, W. Choi, Structural, electrical, magnetic, and electronic structure studies of PrFe1−xNixO3 (x≤0. 5), J. App. Phys. 102 (2007) 073707-073715.
4. W.R. Cannon, M. Yoshimura, J. Mizusaki, T. Sasamoto, R.L. Pober, I. Hart, H.K. Bowen, and J.F. Louis, Properties and Test Results of Super-Hot Wall Electrode Materials, Proc. 17th Symp. Eng. Aspects of MHD, Stanford University, March. (1978) 17.
5. J. Mizusaki, W.R. Cannon, and H.K. Bowen, Electrochemical Degradation of Ceramic Electrodes, J. Am. Ceram. Soc. 63 (1980) 391-397.
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