Thermal Expansion, Oxygen Non-Stoichiometry and Diffusion Mobility in some Ferrites-Nickelites

Author:

Vashook Vladimir1,Rebello Jean1,Chen J.Y.1,Vasylechko Leonid2,Trots Dmytro3,Zosel J.4,Guth Ulrich1

Affiliation:

1. Dresden University of Technology

2. Lviv Polytechnic National University

3. Universität Bayreuth

4. Kurt-Schwabe Research Institute

Abstract

Crystal structure,thermal expansion, oxygen non-stoichiometry, electrical conductivity and diffusion characteristics of two analogous LaFe0.7Ni0.3O3‑d and PrFe0.7Ni0.3O3‑d compositions were investigated depending on temperature (201000 °C) and oxygen partial pressure (0.6–21000 Pa). The found oxygen diffusion and oxygen exchange coefficients for the both compositions at similar conditions are near to each other and varied in the range of 110‑7110‑5 cm2s‑1 and 510‑6110‑4 cms‑1, respectively.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

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