Effects of Raw Material Contaminants on the Ferrosilicon Melting Process in the Submerged Arc Furnace

Author:

Machulec Bolesław1,Bialik Wojciech1

Affiliation:

1. Silesian University of Technology

Abstract

Based on the Minimum Gibbs Free Enthalpy algorithm (FEM) and a model of reaction zones located around electrode tips in the submerged arc furnace, an analysis of the raw material chemical composition influence on the ferrosilicon smelting process was carried out. A model of the ferrosilicon process in the submerged arc furnace is a system of two closed isothermal reactors: an upper one with a lower temperature T1, and a lower one with a higher temperature T2. Between the reactors and the environment as well as between the reactors inside the system, a periodical exchange of mass occurs at the moments when the equilibrium state is reached. Based on the model, sets of calculations were performed: for a Fe-Si-O-C system and, subsequently, for a more complex Fe-Si-O-C-Al-Ca-Mg-Ti system. For both systems, the energy and mass balance values were calculated and the effects of raw material contaminants on the efficiency of the ferrosilicon melting process were determined.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

Reference6 articles.

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3. N.K. Batra, Modelling of ferrosilicon smelting in submerged arc furnace, Iron and Steelmaking 39 (5) (2003) 399-404.

4. G. Eriksson, T. Johansson, Thermodynamic Studies of Chemical and Thermal Equilibrium Calculations for a Quantitative Description of a Non-Isothermal Reactor with Application to the Silicon Arc Furnace, Scandinavian Journal of Metallurgy 7 (1978).

5. A. Roine, HSC Chemistry 7. 0 User's Guide, vol. 1/2 Chemical Reaction and Equilibrium Software with Extensive Thermochemical Database and Flow sheet Simulation, Outotec, Finland, (2007).

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