High-Pressure Synthesis of Skutterudite-Type Thermoelectric Materials

Author:

Sekine Chihiro1,Kato Hirotaka1,Kawamura Yukihiro1,Lee Chul Ho2

Affiliation:

1. Muroran Institute of Technology

2. National Institute of Advanced Industrial Science and Technology

Abstract

We have developed a manufacturing system by combination of high-pressure synthesis method using a multi-anvil press, and spark plasma sintering (SPS) method. By means of the system, we have succeeded in synthesizing new filled skutterudite-type thermoelectric materials MmxCo4Sb12 (Mm=mischmetal). The thermoelectric properties of partially filled skutterudite compounds MmxCo4Sb12 synthesized under high pressure have been investigated. The Seebeck coefficient of MmxCo4Sb12 shows negative value, which means n-type conductivity. The highest dimensionless figure of merit ZT value is 0.25 for Mm0.6Co4Sb12 at 700 K.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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