Abstract
Activated carbon has been successfully prepared from coconut shell charcoal using novel dry mechano-chemical activation with KOH and planetary ball mill. The combination of chemical activation and mechanical activation on coconut shell charcoal is found to increase its micopore volume and surface size. These increase yielded to a high adsorption capacity which was measured at 298 K and 268 K found to be 0.6 wt. % for activated carbon. The adsorption experiments were conducted using constant-volume-variable-pressure (CVVP) test. Adsorption parameters were calculated using adsorption isotherm models: Langmuir and Dubini-Asthakov models and were found in good agreement for type II adsorption phenomenon. It is also found that the adsorption capacity of activated carbon was suitable for hydrogen storage application.
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science
Reference10 articles.
1. Serrano, Elena, Guillermo Rus, and Javier Garcia-Martinez, Nanotechnology for Sustainable Energy, Renewable and Sustainable Energy Reviews 13 (2009): 2373-2384.
2. Jiménez, Vicente, Paula Sánchez, José Antonio Díaz, José Luis Valverde, and Amaya Romero, Hydrogen Storage Capacity on Different Carbon Materials, Chemical Physics Letters 485 (2010): 152–155.
3. Niemann, Michael U., Sesha S. Srinivasan, Ayala R. Phani, Ashok Kumar, D. Yogi Goswami, and Elias K. Stefanakos, Nanomaterials for Hydrogen Storage Applications, Journal of Nanomaterials (2008): 1-9.
4. Ahmadpour, D.D. Do, The characterization of activated carbons with oxygen and nitrogen surface groups, Carbon, 35 (12) (1997), p.1723–1732.
5. Tsai, Wei-Tek, C. Y. Chang, and S. L. Lee, A low cost adsorbent from agricultural waste corn cob by zinc chloride activation, Bioresource Technology 64.3 (1998): 211-217.
Cited by
11 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献