Microstructure Control of Barium Titanate – Potassium Niobate Solid Solution System Ceramics by MPB Engineering and their Piezoelectric Properties

Author:

Shimizu Shigehito1,Kumada Nobuhiro1,Nakashima Kouichi1,Fujii Ichiro1,Tanaka Daisuke2,Furukawa Masahito2,Kuroiwa Yoshihiro3,Suzuki Tohru S.4,Uchikoshi Tetsuo4,Sakka Yoshio4,Wada Satoshi1

Affiliation:

1. University of Yamanashi

2. TDK Corporation

3. Hiroshima University

4. National Institute For Materials Science

Abstract

Effect of the microstructural homogeneity of 0.5 BaTiO3 - 0.5 KNbO3 (0.5BT-0.5KN) solid solution ceramics on the dielectric and piezoelectric properties was investigated. Microstructure of a sample prepared by a conventional sintering method was homogenous, and the room temperature crystal structure was assigned to cubic Pm3m symmetry and therefore the sample was paraelectric. On the other hand, microstructure of samples prepared by a two-step sintering method was inhomogeneous, that is, it was made of BT and KN grains. The large electric field piezoelectric constant d33* increased with increasing interface area.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference5 articles.

1. M. Demartin Maeder and D. Damjanovic: in Piezoelectric Materials in Devices, ed. N. Setter (N. Setter, Lausanne, 2002) p.389.

2. R.J. Bratton, T.Y. Tien, J. Am. Ceram. Soc., 50, 90-93 (1967).

3. S. Wada, M. Nitta, N. Kumada, D. Tanaka, M. Furukawa, C. Moriyoshi and Y. Kuroiwa: Key Eng. Mater. (2009) in press.

4. S. Wada, M. Nitta, N. Kumada, D. Tanaka, M. Furukawa, S. Ohno, C. Moriyoshi, and Y. Kuroiwa: Jpn. J. Appl. Phys. 47 (2008) 7678.

5. S. Kondo, C. Moriyoshi, Y. Kuroiwa and S. Wada: Key Eng. Matt. Vol. 421-422 (2010) p.506.

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