Photo-Instability in a Binary Mixture of Banana-Shaped and Rod-Shaped Liquid Crystals

Author:

Chen Lan Li1,Zhai Bao Gai2,Huang Yuan Ming2

Affiliation:

1. Nanyang Institute of Technology

2. Changzhou University

Abstract

By triangular wave method, we studied the effects of ultraviolet irradiation on the polarization of a binary liquid crystal mixture. The mixture was comprised of 94 wt% of banana-shaped liquid crystal 4-chloro-1,3-phenylene bis [4-(4-n-tetradecyl) phenylimino methyl] benzoate and 6 wt% of an azo-containing rod-shaped liquid crystal hexanoic acid 4-(4-ethoxy-phenylazo)-phenyl ester. Under the 365 nm irradiation for 40 minutes, the polarization of the mixture was observed to decrease 10% although the component of the banana-shaped liquid crystal was photostable. Our results demonstrated that photolysis took place in the component of azo-containing rod-shaped liquid crystal.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference10 articles.

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3. Y. M. Huang, L. Chen, F. F. Zhou and B. G. Zhai, in: New Trends in Fluid Mechanics Research, edited by F. G. Zhuang, J. C. Li, Tsinghua University Press & Springer, Beijing (2007).

4. Y. M. Huang, Trends in Optics and Photonics Series Vol. 99 (2005), p.288.

5. D.H. Paik, J.S. Baskin, N.J. Kim and A.H. Zewail, J. Chem. Phys. Vol. 125 (2006), p.133408.

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