Properties of Conversion Coating of Magnesium Alloys by a Phosphate-Permanganate Solution

Author:

Wu Shu Sen1,Zhao Ming2,Luo Ji Rong1,Mao You Wu1

Affiliation:

1. Huazhong University of Science and Technology

2. North China University of Technology

Abstract

A chromium-free conversion coating for AZ91D magnesium alloys has been obtained by using a phosphate-permanganate solution. Examinations have been carried out on the conversion coating for morphology, composition, adhesion force and corrosion resistance. Results show that the conversion coatings are relatively uniform and continuous, with thickness from 7µm to 10µm. They exhibit good adhesion to matrix and have some non-penetrate tiny holes on the surface. The main elements of the conversion coating of AZ91D alloy are Mg、O、P、K、Al、Mn. Results of corrosion resistance test indicate that the corrosion resistance of the conversion coating by phosphate-permanganate solution is in match to that of the conversion coating formed in a chromate solution, but for the corrosion resistance after painting, the former is better than the later.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference4 articles.

1. E. Ghali, W. Dietzel et al. J. of Mater. Eng. and Performance, Vol13 (1), (2004), p.7.

2. JIS K 5400. JIS Japanese Industrial Standard Testing Methods for Paints.

3. ASTM B117-97, Standard Practice for Operating Salt Spray (fog) Apparatus.

4. X. Wu, S. Wu et al. Special Casting & Nonferrous Alloys ,Vol27(5), (2002), p.51.

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