Ultrasonic-Assisted Deprotection of <i>tert</i>-Butyldimethylsilyl Ethers with Bromotrichloromethane in Methanol-Reference-Cited by-同舟云学术

Ultrasonic-Assisted Deprotection of tert-Butyldimethylsilyl Ethers with Bromotrichloromethane in Methanol

Published:2013-10 Issue: Volume:830 Page:230-233
ISSN:1662-8985
Container-title:Advanced Materials Research
language:
Short-container-title:AMR

Author:

Sun Jian¹,Gong Shan Shan¹,Sun Qi¹

Affiliation:

1. Jiangxi Science and Technology Normal University

Abstract

Treatment of tert-butyldimethylsilyl (TBDMS) ethers of nucleosides with bromo-trichloromethane (CBrCl3) in methanol under ultrasonic conditions provides a mild and efficient method for desilylation. The experimental results showed that the employment of ultrasonic could notably improve the reaction efficiency compared with thermal heating condition.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Link

https://www.scientific.net/AMR.830.230.pdf

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