Affiliation:
1. Universiti Teknologi MARA
2. Universiti Teknologi MARA (UiTM)
Abstract
Thin films of poly (ethylene oxide) (PEO), poly (methyl methacrylate) (PMMA) and selected blends of PEO/PMMA with and without the addition of LiClO4 were prepared using solution casting technique. The presence of a single Tg which corresponds closely to that of the Gordon Taylor equation confirms the miscibility of both the salt-free and salt-doped blends. The Tgs and the ion conductivity (σ) at room temperature of PEO, PMMA and the PEO/PMMA blends generally increase with ascending salt concentration (Y). Variations in the σ value as a function of Y for all the three systems correlate closely with their respective Tg results. PMMA-salt complex records the lowest σ value at all salt concentrations. PEO/PMMA/LiClO4 blend with 75 wt% PEO exhibits the highest σ value of 5 x 10-7 S cm-1 at Y = 0.10. The σ value of the blend-salt system is observed to be slightly lower than that of the PEO-salt system. This is due to reduced segmental motion cause by increased Tg of the blend and a decrease in free ions in the amorphous phase of PEO as a small amount of the salt is solvated by PMMA in the blend. Therefore, the percolation path lies in the amorphous PEO rich phase of the blend.
Publisher
Trans Tech Publications, Ltd.
Cited by
10 articles.
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