A Novel Approach to Prepare Fluorinated Polyether Glycol Using Phase-Transfer Catalysts

Author:

Li Ying1,Song Wei1,Wang Xia1

Affiliation:

1. University of Shanghai for Science and Technology

Abstract

The goal of this work has been the synthesis of novel fluorine-containing glycidyl ether based on 3, 3, 2, 2-tetrafluoropropanol (TFP) and epichlorohydrin (ECH) as the starting materials under condition of TBAB (Tetrabutylammonium bromide) catalyst. Furthermore, a novel fluorinated polyether glycol was successfully produced by the above synthesized fluorine-containing glycidyl ether. The structure of the products was characterized by 1H-NMR and IR spectrum. The number average molecular weight was measured by GPC.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference10 articles.

1. Matuszczak, S. and Feast, W. J.:J. Fluorine Chem., 2000, vol. 102, p.269.

2. Vatsuro, K.V. and Mishchenko, G.L.: Imennye reaktsiiv organicheskoi khimii (Named Reactions in Organic Chemistry), Moscow: Khimiya, 1976, p.403.

3. Li Ji ming, Wang Xia, Song Ai-ten, Yu Zhi-zhao: Synthesis of octyl glycidyl ether-a reactives diluent for epoxy resin. Thermosetting Resin, 1992, (1): 7-10.

4. Jiang Wei he, Qu Kai jia, Tang Zhaolan: Preparation of 1, 2-cyclohexanediol diglycidyle. Thermosetting Resin, 2004, Vol. 19, pp.8-12.

5. C.M. Starks, M. Liotta, M. Halpern: Phase Transfer Catalysis: Fundamentals, Applications and Perspectives, Chapman and Hall, New York, (1994).

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