Synthesis and Characterization of Tri-N-Octylamine-Intercalated α-Zirconium Phosphate

Author:

Chen Ruo Yu1,Yao Wei1,Wang Hong Ning1,Wang Jian Wu1,Zhong Jing1

Affiliation:

1. Changzhou University

Abstract

Tri-n-octylamine-intercalated α-zirconium phosphate (TOA-ZrP) was prepared in the presence of (C4H9)4NOH for the first time. The interlayer distance of (C4H9)4NOH-intercalatedα-zirconium phosphate (B-ZrP) is 14.7 Å, larger than that ofα-ZrP (7.6 Å). The TOA-ZrP sample is highly crystallized with the interlayer distance of 22.3 Å. The molar ratio of TOA toα-ZrP in the intercalation composite was found to be 1/1.21. The composite can find application in solid extraction.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference11 articles.

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3. G. Alberti and U. Costantino: Intercalation Chemistry (Academic Press, New York 1982).

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5. M. Danjo, M. Tsuhako, H. Nakayama, T. Eguchi, N. Nakamura, S. Yamaguchi, H. Nariai and I. Motooka: Bull. Chem. Soc. Jpn. Vol. 70 (1997), p.1053.

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