The Catalysis of 3, 8-Substituted Cobalt (II) Deuteroporphyrin Dimethyl Esters to the Oxidation of Cyclohexane by Air

Author:

Xu Shi Chao1,Hu Bing Cheng1,Cui Qiao Li1,Hu Tian Jing1,Huang Xiu You1,Liu Zu Liang1

Affiliation:

1. Nanjing University of Science and Technology

Abstract

A variety of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esterswere synthesized and used as catalysts in the oxidation of cyclohexane. The effect of substituents on catalytic activities of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esters were investigated. The results showed that the catalytic activities were influenced by the electron effects and steric effects of substituents and the thermal stability of catalysts.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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